thesis:co2dissolution

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thesis:co2dissolution [2016/01/12 20:18] a.hartmannthesis:co2dissolution [2018/08/13 12:37] a.hartmann
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-===== Dissolution of CaCO3 as non-steady state phenomenon? The effect of precipitation characteristics and soil on CaCO3 relocation and its relevance for karst formation =====+===== Dissolution of CaCO3 as non-steady state phenomenon? The effect of precipitation characteristics and soil on CaCO3 relocation and its relevance for karst formation (L. Freiberg)=====
 == Motivation == == Motivation ==
 Dissolution of CaCo3 in calcareous soils is mainly governed by CO2 which forms a weak but ubiquitous acid in the aqueous phase. It is generally assumed, that it is mainly the CO2 concentration and the discharge control the re-location of CaCO3, and thus the further formation of soil and karst. In most cases soil and karst systems are considered to be static and that the CaCO3 dissolution process is a steady state process, that can be derived from the amount of water infiltrating into the deeper soil or karst system, and the mean CO2 concentration in the deeper soil (Williams 1983). Dissolution of CaCo3 in calcareous soils is mainly governed by CO2 which forms a weak but ubiquitous acid in the aqueous phase. It is generally assumed, that it is mainly the CO2 concentration and the discharge control the re-location of CaCO3, and thus the further formation of soil and karst. In most cases soil and karst systems are considered to be static and that the CaCO3 dissolution process is a steady state process, that can be derived from the amount of water infiltrating into the deeper soil or karst system, and the mean CO2 concentration in the deeper soil (Williams 1983).
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 We want to test the effect of different precipitation regimes on CaCO3 re-location using soil samples from different sites (e.g. Schönberg, Vogtsburg, Hartheim).The sites will have different characteristics regarding, saturated and unsaturated conductivity, pore structure (preferential flow?), and soil aeration. Soil CO2 will be monitored during the measurements. Re–located CaCO3 seeping from the samples will be quantified. Different precipitation events will be simulated. All technical equipment necessary for construction of the set-up is available. We want to test the effect of different precipitation regimes on CaCO3 re-location using soil samples from different sites (e.g. Schönberg, Vogtsburg, Hartheim).The sites will have different characteristics regarding, saturated and unsaturated conductivity, pore structure (preferential flow?), and soil aeration. Soil CO2 will be monitored during the measurements. Re–located CaCO3 seeping from the samples will be quantified. Different precipitation events will be simulated. All technical equipment necessary for construction of the set-up is available.
 == Betreuung/Supervision ==  == Betreuung/Supervision == 
-Andreas Hartmann, Benedikt Heudorfer, Ciaran Harman (Johns Hopkins University, USA+Andreas Hartmann, Martin Maier (Bodenkunde
 == Special notes == == Special notes ==
 none. none.
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 Maier, M., Schack-Kirchner, H., Hildebrand, E.E., Holst, J., 2010. Pore-space CO2 dynamics in a deep, well-aerated soil. Eur. J. Soil Sci. 61, 877–887 Maier, M., Schack-Kirchner, H., Hildebrand, E.E., Holst, J., 2010. Pore-space CO2 dynamics in a deep, well-aerated soil. Eur. J. Soil Sci. 61, 877–887
 Williams, P.W., 1983. The role of the subcutaneous zone in karst hydrology. Journal of Hydrology 61, 45–67 Williams, P.W., 1983. The role of the subcutaneous zone in karst hydrology. Journal of Hydrology 61, 45–67
-{{tag>master labor offen daten gelaende}}+{{tag>master labor vergeben daten gelaende}}
  • thesis/co2dissolution.txt
  • Zuletzt geändert: 2020/02/18 13:56
  • von a.hartmann